Examine the chemistry of burning fuels and the role of oxygen in releasing energy.
Have you ever wondered why a campfire leaves behind piles of ash and soot, while a gas stove seems to make fuel vanish into thin air? The secret lies in how perfectly—or imperfectly—we burn our fuel.
To start a fire, you need three specific ingredients: Fuel, Oxygen, and Heat. This is known as the Fire Triangle. If you remove any one of these, the reaction stops immediately. In chemistry, combustion is an exothermic reaction, meaning it releases energy into the surroundings as heat and light. Most common fuels are hydrocarbons—molecules made entirely of hydrogen and carbon atoms, such as methane (), propane (), or butane ().
Quick Check
If a firefighter uses a carbon dioxide extinguisher to displace the air around a fire, which part of the Fire Triangle are they removing?
Answer
Oxygen
When a hydrocarbon burns in a plentiful supply of oxygen, we call it complete combustion. This is the most efficient way to release energy from fuel. In this reaction, the carbon atoms are fully oxidized to form carbon dioxide (), and the hydrogen atoms are oxidized to form water (). A hallmark of complete combustion is a clean, blue flame, like the one you see on a well-adjusted gas stove.
Let's balance the equation for burning methane ():
Quick Check
What are the only two chemical products of complete combustion of a hydrocarbon?
Answer
Carbon dioxide () and water ().
If the oxygen supply is limited, the fuel cannot burn completely. This is incomplete combustion. Because there isn't enough oxygen to turn all the carbon into , other products form. These include carbon monoxide (), a colorless and odorless toxic gas, and soot (pure carbon, ). Incomplete combustion is less efficient, releasing less heat energy, and is characterized by a flickering yellow or orange flame.
Imagine you are using a camping stove. You notice the bottom of your pot is covered in a black, powdery substance.
1. Identify the substance: The black powder is soot (unburnt carbon). 2. Determine the cause: Soot is a product of incomplete combustion. 3. Conclusion: The stove is not receiving enough oxygen to burn the fuel completely. This makes the stove less efficient and potentially dangerous due to production.
Balance the complete combustion of propane ():
Which of the following is a product of incomplete combustion but NOT complete combustion?
What is the correct coefficient for when balancing the complete combustion of methane ()?
A blue flame indicates that the combustion reaction is likely incomplete.
Review Tomorrow
In 24 hours, try to sketch the Fire Triangle from memory and write the balanced equation for the combustion of methane.
Practice Activity
Try to balance the combustion equation for Ethane (). Hint: You may need to use a fraction or double all coefficients to get whole numbers!